Suzhou nanometer developed carbon nanotube array Schottky solar cells

In a recent breakthrough, Li Qingwen’s team at the Suzhou Institute of Nanotechnology and Nanobionics, Chinese Academy of Sciences, has made significant progress in developing nanotube array photovoltaic cells. The researchers used a carbon nanotube film directly drawn from a spinnable array as a transparent electrode, achieving a device efficiency of 10.5%. This achievement was published in a special edition of *Small*, highlighting the potential of this technology. According to *Materials Views*, Schottky-type photovoltaic cells can be created by transferring a conductive film onto a silicon surface. When light hits the device, electron-hole pairs are separated at the Schottky junction formed between the film and silicon, enabling efficient photoelectric conversion. Compared to traditional silicon-based solar cells, this hybrid approach simplifies the manufacturing process, potentially lowering costs significantly. Carbon nanotube films have become a key focus due to their low surface resistance, tunable transparency, and excellent environmental stability. Li Qingwen explained that the high structural uniformity, transparency, and electrical properties of the nanotube arrays contributed to a smooth development process. Early devices had an efficiency of around 6%, but through extensive experimentation, the team improved performance. They tested different types of carbon nanotubes, including double-walled and multi-walled varieties, finding that double-walled structures performed best. Additionally, they explored how the orientation of the nanotubes affected device efficiency, discovering that aligned structures increased the contact area between the nanotubes and silicon, improving charge transport and overall performance. To further enhance efficiency and stability, future research must focus on optimizing the interface between carbon nanotubes and silicon. If the connection is only physical, it may reduce the efficiency of charge collection. Improving the quality of the nanotubes—such as reducing defects and achieving more controlled structures—will also play a crucial role in enhancing device performance. Finally, Li Qingwen acknowledged the contributions of Dr. Jiangjiang Jiang, who led most of the experiments, as well as the support from Professors Zheng Xinhe and Sun Baoquan at Suzhou University in refining the device structure and analyzing data. All co-authors participated in data interpretation, discussions, and the final paper revision.

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